Application of graphene solution in epoxy paint systems
Abstract
This study focuses on applying graphene solution to epoxy paint systems to enhance corrosion protection for steel structures. Graphene material is dispersed in xylene solvent to create a solution with high dispersion stability. The graphene solution is added to the two-component epoxy paint system using a stirring method. Test results show that the paint film is resistant to alkali, acid, salt water, and heat. Notably, samples with high graphene content increased impact resistance from 50 to 60 kg.m compared to samples without graphene. The immersion test in 5% NaCl solution (salt spray test) after 2 months showed that samples with graphene exhibited no blistering or rusting, while control samples began to show these signs. Accelerated weathering tests also demonstrated that samples with graphene had better UV resistance with less gloss reduction. When applied to commercial paints, graphene improved film hardness from F, HB, H to 2H and 3H, reduced wear resistance from 5.65% to 2.43%, and increased adhesion strength from 10.2 MPa to 13.5 MPa. Salt spray testing after 816 hours indicated that samples with graphene demonstrated superior anti-corrosion resistance. The product has been registered under the Peraphene trademark and was showcased at the 2024 high-tech exhibition.
References
Nguyễn Nam Thắng, Nguyễn Mạnh Hồng và Phan Văn Chương, “Đánh giá chất lượng các hệ sơn phủ chống ăn mòn kết cấu thép vùng biển Việt Nam”, Tạp chí Khoa học Công nghệ Xây dựng, Số 3, 2011.
Tullio Monetta, Annalisa Acquesta, and Francesco Bellucci, “Graphene/epoxy coating as multifunctional material for aircraft structures, aerospace”, Aerospace, Volume 2, Issue 3, pp. 423 - 434, 2015. DOI: 10.3390/aerospace2030423.
Samarah V. Harb, Sandra H. Pulcinelli, Celso V. Santilli, Kevin M. Knowles, and Peter Hammer, “A comparative study on graphen oxide and carbon nanotube reinforcement of PMMA-Siloxane-Silica anticorrosive coatings”, ACS Applied Materials & Interfaces, Volume 8, Issue 25, pp. 16339 - 16350, 2016. DOI: 10.1021/acsami.6b04780.
Sepideh Pourhashem, Mohammad Reza Vaezi, Alimorad Rashidi, and Mohammad Reza Bagherzadeh, “Exploring corrosion protection properties of solvent based epoxy-graphen oxide nanocomposite coatings on mild steel”, Corrosion Science, Volume 115, pp. 78 - 92, 2017. DOI: 10.1016/j.corsci.2016.11.008.
Xin Li, Bing Yu, Jie Chen, Dongxia Huo, Jun Liu, and Ding Nan, “Optimized functionalization of graphene oxide for enhanced mechanical properties in epoxy resin composites”, Coatings, Volume 14, Issue 5, 2024. DOI: 10.3390/coatings14050609.
Seyed Rasoul Mousavi, Sara Estaji, Hediyeh Kiaei, Mohammad Mansourian-Tabaei, Sasan Nouranian, Seyed Hassan Jafari, Holger Ruckdäschel, Mohammad Arjmand, and Hossein Ali Khonakdar, “A review of electrical and thermal conductivities of epoxy resin systems reinforced with carbon nanotubes and graphene-based nanoparticles”, Polymer Testing, Volume 112, 2022. DOI: 10.1016/j.polymertesting.2022.107645.
Sheetal Gulia, Md Moniruzzaman, and Atanu Panda, “Approaches in graphene-based nanocomposites: Synthesis, modification, and multifaceted applications”, FlatChem, Volume 48, 2024. DOI: 10.1016/j.flatc.2024. 100761.
Siti Shafiah Shazali, Ahmad Amiri, Mohd Nashrul Mohd Zubir, Shaifulazuar Rozali, Mohd Zakuan Zabri, Mohd Faizul Mohd Sabri, and Mohammadreza Soleymaniha, “Investigation of the thermophysical properties and stability performance of non-covalently functionalized graphene nanoplatelets with Pluronic P-123 in different solvents”, Materials Chemistry and Physics, Volume 206, pp. 94 - 102, 2018. DOI: 10.1016/j.matchemphys.2017.12.008.
Sutripto Majumder, Ankita Meher, Srikanta Moharana, and Ki Hyeon Kim, “Graphene nanoribbon synthesis and properties in polymer composites: A review”, Carbon, Volume 216, 2024. DOI: 10.1016/j.carbon.2023.118558.
Sabih Qamar, Naveed Ramzan, and Waqas Aleem, “Graphene dispersion, functionalization techniques and applications: A review”, Synthetic Metals, Volume 307, 2024. DOI: 10.1016/j.synthmet.2024.117697.
Lawrence E. Nielsen, “Models for the permeability of filled polymer systems”, Journal of Macromolecular Science Part A: Chemistry, Volume 1, Issue 5, pp. 929 - 942, 1967. DOI: 10.1080/10601326708053745.
Hao Li, Qin-Hao Zhang, and Xian-Ze Meng, Hao-Jie Yan, Hui-Song Hu, Lian-Kui Wu, and Fa-He Cao, “Active/passive protection and anti-UV waterborne epoxy coatings based on low defect functionalized PDA-GO-CeO2 material for excellent corrosion control”, Chemical Engineering Journal, Volume 479, 2024. DOI: 10.1016/j.cej.2023.147859.

1. The Author assigns all copyright in and to the article (the Work) to the Petrovietnam Journal, including the right to publish, republish, transmit, sell and distribute the Work in whole or in part in electronic and print editions of the Journal, in all media of expression now known or later developed.
2. By this assignment of copyright to the Petrovietnam Journal, reproduction, posting, transmission, distribution or other use of the Work in whole or in part in any medium by the Author requires a full citation to the Journal, suitable in form and content as follows: title of article, authors’ names, journal title, volume, issue, year, copyright owner as specified in the Journal, DOI number. Links to the final article published on the website of the Journal are encouraged.